Osmium tetroxide

ReagentPlus^®, 99.8%

Sinônimo(s):

Osmium(VIII)-oxide, ‘Osmic acid’

Fórmula linear:

OsO₄

Número CAS:

20816-12-0

Peso molecular:

254.23

Número EC:

244-058-7

Número MDL:

MFCD00011150

ID de substância PubChem:

329751973

NACRES:

NA.55

densidade de vapor

8.8 (vs air)

Nível de qualidade

200

pressão de vapor

7 mmHg ( 20 °C)

linha de produto

ReagentPlus^®

Ensaio

99.8%

forma

crystalline
powder

reaction suitability

reagent type: oxidant

pb

130 °C (lit.)

pf

39.5-41 °C (lit.)

temperatura de armazenamento

2-8°C

SMILES string

O=[Os](=O)(=O)=O

InChI

1S/4O.Os

InChI key

VUVGYHUDAICLFK-UHFFFAOYSA-N

Descrição geral

Osmium tetroxide (OsO₄) is widely employed as a catalyst in various organic reactions.[1] Stereochemical aspects of the OsO₄ assisted oxidation of allylic alcohols and their derivatives have been reported.[2] Its reaction with olefins has been investigated.[3] It participates as a catalyst for oxidizing fluoroquinolones, via reaction with potassium hexacyanoferrate(III) in alkaline medium. Kinetics of this oxidation reaction was studied.[1]

Aplicação

Osmium tetroxide may be employed as a catalyst for the hydroxylation of sterically hindered olefins.[4]

Osmium tetroxide may be used in the following processes:

To promote the lactonization of alkenols to lactones.[5]

To mediate the selective oxidative cleavage of olefins by oxone to form the corresponding ketones or carboxylic acids.[6]

Dihydroxylation of mono-trans-di, and trisubstituted olefins to form 1,2-diols with high enantioselectivity in the presence of chiral amines.[7]

Widely used oxidizer for visualizing cells in microscopy. Promotes oxidative cleavage of graphene layers in carbon nanotubes creating the possibility of opening ′windows′ in fullerene cages.[8]

Informações legais

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