Cloreto De Estanho IV 98% - 250 Gr - Sigma
Código: 16450
Tin(IV) chloride
98%
Sinônimo(s):
Stannic chloride fuming
Fórmula linear:
SnCl4
Número CAS:
Peso molecular:
260.52
Número EC:
Número MDL:
ID de substância PubChem:
densidade de vapor
9 (vs air)
Nível de qualidade
pressão de vapor
10 mmHg ( 10 °C)
18.6 mmHg ( 20 °C)
20 mmHg ( 22 °C)
Ensaio
98%
forma
liquid
reaction suitability
core: tin
reagent type: Lewis acid
reagent type: catalyst
pb
114 °C (lit.)
pf
−33 °C (lit.)
densidade
2.226 g/mL at 25 °C (lit.)
SMILES string
Cl[Sn](Cl)(Cl)Cl
InChI
1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
InChI key
HPGGPRDJHPYFRM-UHFFFAOYSA-J
Descrição geral
Stannic chloride (SnCl4) is a strong Lewis acid widely used as a promoter or catalyst in organic synthesis. It is soluble in most organic solvents.[1]
Aplicação
Stannic chloride can be used to catalyze:
Cyclization of trans β-monocyclohomofarnesic acid to form norambreinolide.[2]
Formation of C-glycosides of aromatic compounds such as thiophene, naphthalene and phloroglucinol trimethyl ether.[3]
Formal [4+2] cycloaddition of 3-ethoxycyclobutanones and allyltrialkylsilanes to form 3-ethoxy-5-[(trialkylsilyl)methyl]cyclohexan-1-ones.[4]
Diastereoselective reaction of δ-alkoxyallylstannanes with aldehydes to form 1,5-diol derivatives.[5]
Other applications of SnCl4:
The SnCl4-2,6-dialkoxyphenols complexes can catalyze cyclization of poylenes, such as 4-(homogeranyl)toluene to form trans-fused tricyclic compound.[6]
SnCl4 can act as a promoter during the reaction of ortho-aminobenzonitriles with β-ketoesters and β-enaminonitriles to form 4-aminoquinolines and 4-aminopyridines, respectively.[7]
SnCl4-silver perchlorate forms an effective catalytic system for the stereoselective of glycosylation 1-O-acetyl glucose.[8]