Ácido Periódico (Periodic Acid) - 100 Gr - Sigma
Código: 22518
Periodic acid ReagentPlus®, ≥99.0%
About This Item
Fórmula empírica (Notação de Hill):
H5IO6
Número CAS:
Peso molecular:
227.94
Número CE:
Número MDL:
Código UNSPSC:
12352106
ID de substância PubChem:
NACRES:
NA.21
Nível de qualidade
linha de produto
ReagentPlus®
Ensaio
≥99.0%
Formulário
powder or crystals
adequação da reação
reagent type: oxidant
técnica(s)
toxicology assay: suitable
pf
122 °C (lit.)
solubilidade
water: 100 mg/mL, clear, colorless
cadeia de caracteres SMILES
OI(O)(O)(O)(O)=O
InChI
1S/H5IO6/c2-1(3,4,5,6)7/h(H5,2,3,4,5,6,7)
chave InChI
TWLXDPFBEPBAQB-UHFFFAOYSA-N
Descrição geral
Periodic acid, an oxoacid of iodine, is commonly used as a strong oxidizing agent. This inorganic acid is soluble in most solvents including water and ether.
Aplicação
Periodic acid can be used in the following reactions:
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Oxidation of alcohols to ketones and aldehydes.
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Oxidation hydroxylamine derivatives.
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Oxidation of arenes to quinones.
It can also be used:
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As a stoichiometric oxidant with chromium (IV) acetate for the oxidation of tertiary C−H bonds to tertiary alcohols.
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In combination with chromium oxide to oxidize primary alcohols to carboxylic acids; alkylbenzenes to benzoic acids; and cyclic benzyl ethers to the corresponding lactones.
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In the selective oxidation of sulfides to sulfoxides using FeCl3 as a catalyst.
Informações legais
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany