p-Benzoquinona

reagent grade, ≥98%, powder or crystals

Sinônimo(s):

Quinona

Sobre este item

Fórmula linear:

C₆H₄(=O)₂

Número CAS:

106-51-4

Peso molecular:

108.09

NACRES:

NA.21

PubChem Substance ID:

57653913

UNSPSC Code:

12352005

EC Number:

203-405-2

MDL number:

MFCD00001591

Beilstein/REAXYS Number:

773967

Assay:

≥98%

Form:

powder or crystals

Nome do produto

p-Benzoquinona, reagent grade, ≥98%

InChI

1S/C6H4O2/c7-5-1-2-6(8)4-3-5/h1-4H

InChI key

AZQWKYJCGOJGHM-UHFFFAOYSA-N

SMILES string

O=C1C=CC(=O)C=C1

biological source

synthetic

grade

reagent grade

vapor density

3.73 (vs air)

vapor pressure

0.1 mmHg ( 25 °C)

assay

≥98%

form

powder or crystals

autoignition temp.

815 °F

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

113-115 °C (lit.)

solubility

water: soluble 14.7 g/L at 20 °C

functional group

ketone

greener alternative category

Aligned

storage temp.

room temp

Quality Level

200

Gene Information

human ... ACHE(43), BCHE(590), CES1(1066)

General description

p-Benzoquinone (PBQ) is a cyclic conjugated diketone. Its high-resolution photoelectron spectrum has been reported.[1] The visible and near ultraviolet spectra of PBQ have been recorded and analyzed.[2] Its addition as coagent has been reported to enhance the crosslinking rate of polypropylene initiated by the pyrolysis of peroxides.[3] Its impact on hemoglobin (Hb) has been investigated based on immunoblots and mass spectral analysis of a smoker′s blood.[4]

Free radical inhibitor

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

p-Benzoquinone may be used to form benzofuranone derivatives on reacting with anilides of β-aminocrotonic acids via Nenitzescu reaction.[5]

Dienophile employed in Diels-Alder cycloadditions to form naphthoquinones,[6] and 1,4-phenanthrenediones.[7]

Oxidant used in first step of greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine.