3-Chloroperbenzoic acid ≤77%

Sinônimo(s):

meta-Chloroperbenzoic acid, 3-Chloroperoxybenzoic acid, MCPBA

Sobre este item

Fórmula linear:

ClC₆H₄CO₃H

Número CAS:

937-14-4

Peso molecular:

172.57

UNSPSC Code:

12352302

NACRES:

NA.22

PubChem Substance ID:

24856527

MDL number:

MFCD00002127

Beilstein/REAXYS Number:

608317

Assay:

≤77%

Form:

solid

Quality Segment

200

assay

≤77%

form

solid

reaction suitability

reagent type: oxidant

mp

69-71 °C (lit.)

functional group

chloro, hydroperoxide

storage temp.

2-8°C

SMILES string

OOC(=O)c1cccc(Cl)c1

InChI

1S/C7H5ClO3/c8-6-3-1-2-5(4-6)7(9)11-10/h1-4,10H

InChI key

NHQDETIJWKXCTC-UHFFFAOYSA-N

General description

3-Chloroperbenzoic acid is a strong oxidizing agent mainly used for the epoxidation of alkenes and also in the Baeyer-Villiger oxidation of ketones to esters.

Application

Effective oxidant for epoxidizing di-, tri-, and tetra-substituted olefins.

3-Chloroperbenzoic acid has been used in the oxidation of N-p-tolylsulfinyl-(E)-1-phenylethylideneimine to N-p-tolylsulfonyl (E)-1-phenylethylideneimine using dichloromethane as a solvent. It has also been used in the preparation of mono- and di-epoxy-functionalized poly(3-hydroxybutyrate)-based reactive polymers. MCPBA is also an effective oxidizing agent for conversion of α-amide substituted polyesters to their corresponding polysulfones with tunable thermal properties.

Other Notes

remainder 3-chlorobenzoic acid and water